| 角色 | 饰演者 | 角色介绍 |
| Napoleon Solo? (104 episodes 1964-1968) | 罗伯特·沃恩 | |
| Illya Kuryakin? (100 episodes 1964-1968) | 大卫·麦考姆 | |
| Alexander Waverly? (96 episodes 1964-1968) | Leo G. Carroll | |
| Lisa Rogers (12 episodes 1967-1968) | Barbara Moore | |
| Wanda? (11 episodes 1966-1967) | Sharyn Hillyer | |
| Sarah? (8 episodes 1965-1966) | Leigh Chapman | |
| Karate Killer? (6 episodes 1966-1967) | Dick Crockett | |
| Imogen Smythe? (5 episodes 1964-1967) | 吉尔·爱兰德 | |
| Parviz? (5 episodes 1965-1966) | David Sheiner | |
| Andy Watson? (5 episodes 1964-1966) | Woodrow Parfrey | |
| Inspector Fiamma? (5 episodes 1965-1967) | Richard Angarola | |
| Cashier? (5 episodes 1965-1966) | Charles Giorgi | |
| Croupier? (5 episodes 1965-1966) | Tom Curtis | |
| 'Doc' Terwilliger? (5 episodes 1964-1967) | Stuart Nisbet | |
| Gloved Thrushman? (5 episodes 1965-1967) | David Armstrong | |
| Prof. David Garrow? (4 episodes 1965-1968) | 丹·奥赫里奇 | |
| Yvonne? (4 episodes 1966-1967) | Danielle De Metz | |
| Croupier? (4 episodes 1965-1967) | Peter Balakoff | |
| Heather McNabb (4 episodes 1964) | May Heatherly | |
| Fred Score? (4 episodes 1964-1967) | Will J. White |
