| 角色 | 饰演者 | 角色介绍 |
| Tony Stark? (47 episodes 2008-2012) | Adrian Petriw | |
| Pepper Potts (43 episodes 2008-2012) | Anna Cummer | |
| War Machine? (44 episodes 2008-2012) | 丹尼尔·巴孔 | |
| Iron Man Onboard Computer? (16 episodes 2008-2012) | Lisa Ann Beley | |
| Gene Khan? (16 episodes 2008-2012) | Vincent Tong | |
| Obadiah Stane? (11 episodes 2008-2011) | Mackenzie Gray | |
| Whitney Stane? (11 episodes 2008-2011) | Kristie Marsden | |
| Roberta Rhodes (9 episodes 2008-2012) | Catherine Lough Haggquist | |
| Justin Hammer? (9 episodes 2011-2012) | Michael Adamthwaite | |
| Happy Hogan? (9 episodes 2008-2012) | Alistair Abell | |
| Howard Stark (7 episodes 2008-2012) | 弗雷德·亨德森 | |
| Nick Fury (7 episodes 2009-2012) | Dean Redman | |
| Sasha (6 episodes 2011-2012) | Paula Lindberg | |
| Maria Hill? (6 episodes 2009-2012) | Paulina Gillis | |
| Mr. Fix? (5 episodes 2009-2012) | Donny James Lucas | |
| O'Brian? (5 episodes 2008-2011) | Brian Drummond | |
| Black Widow? (4 episodes 2011-2012) | Ashleigh Ball | |
| Tricia (3 episodes 2008-2009) | Rebecca Shoicet | |
| Clint Barton? (3 episodes 2009-2012) | Andrew Francis |
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